Honors Chemistry                                                        Name______________________

Nomenclature Packet—PMP 2—Non-ionic compounds

Mr. McAfoos                                                               Period______ Date____________

 

There are two skills that you must master, writing the formula of a compound when you are given the name and writing the name of a compound when you are given the formula.

 

Naming Formulas:

Non-ionic compounds are fairly simple to name.  We use a system of number prefixes to tell the amount of a particular element.  The prefixes are:

            mono - 1           hexa - 6

            di – 2                hepta - 7

            tri – 3              octa - 8

            tetra – 4          nona - 9

            penta – 5         deca - 10

 

For any given compound you simply tell how many and the identity of the elements giving the last element the ending "ide" (it sounds better).

 

Example 1:       P4O10                tetraphosphorus decoxide

 

Note: if an element (such as O) begins with a vowel (other than i) you may drop the last vowel in the prefix.  Decoxide rather than decaoxide)

 

Example 2:       B2H6    diboron hexahydride

 

For compounds that contain only one atom of the first element you may drop the "mono" prefix for the first element only.

 

Example 3:       CO2                  carbon dioxide (not monocarbon dioxide)

 

You must however keep the prefix for all other elements in a compound even if there is only one of them.

 

Example 4:       CO                   carbon monoxide (not carbon oxide)

 

 

Formula Writing:

Since the name of any non-ionic compound contains number prefixes, writing the formula for non-ionic compounds is very straightforward. Simply write what the name says.

 

Example 1:       carbon tetrabromide

no prefix for the carbon so it must be mono (see example 3 above)

tetra = 4 so...   CBr4

 

Example 2: diphosphorus pentasulfide            P2S5

Formula

Name

Formula

Name

1) As4O10

 

 

16) UF6

 

 

2) BrO3

 

 

17) OF2

 

3) BN

 

 

18) ClO2

 

4) N2O3

 

 

19) SiO2

 

5) NI3

 

 

20) BF3

 

6) SF6

 

 

21) N2S5

 

7) XeF4

 

 

22) CO2

 

8) PCl3

 

 

23) SO3

 

 

9) CO

 

 

24) XeF6

 

 

10) PCl5

 

 

25) KrF2

 

 

11) P2O5

 

 

26) BrCl5

 

 

12) S2Cl2

 

 

27) SCl4

 

 

13) ICl2

 

 

28) PF3

 

 

14) SO2

 

 

29) XeO3

 

 

15) P4O10

 

 

30) OsO4

 

 

 

Name

Formula

Name

Formula

Name

Formula

1) chlorine monoxide

 

11) sulfur dioxide

 

 

21) dinitrogen pentasulfide

 

 

2) oxygen difluoride

 

 

12) bromine pentafluoride

 

 

22) carbon monoxide

 

 

3) boron phosphide

 

 

13) disulfur dichloride

 

 

23) sulfur trioxide

 

 

4) dinitrogen monoxide

 

 

14) boron trifluoride

 

 

24) dinitrogen trioxide

 

 

5) nitrogen trifluoride

 

 

15) tetraarsenic decoxide

 

 

25) dinitrogen monoxide

 

 

6) sulfur tetrachloride

 

 

16) silicon tetrachloride

 

 

26) xenon hexafluoride

 

 

7) xenon trioxide

 

 

17) krypton difluoride

 

 

27) sulfur hexafluoride

 

 

8) carbon dioxide

 

 

18) chlorine monoxide

 

 

28) phosphorous pentachloride

 

 

9) diphosphorous pentoxide

 

 

19) silicon dioxide

 

 

29) nitrogen monoxide

 

 

10) phosphorous trichloride

 

 

20) boron trichloride

 

 

30) bismuth trichloride